Binuclear Schiff Base Complex of Manganese(III) as a Neutral Carrier for a Highly Selective Iodide Electrode
نویسندگان
چکیده
منابع مشابه
Binuclear Schiff base complex of manganese(III) as a neutral carrier for a highly selective iodide electrode.
A new highly selective iodide electrode incorporating a binuclear manganese(III) complex, bis(salicylaldehyde-aminopropanol)dichloroaceticdimanganese(III) [Mn(III)(2)-BSAPDCA], as a neutral carrier is described. The electrode displays an anti-Hofmeister selectivity sequence: iodide >> perchlorate > salicylate > thiocyanate > nitrate > bromide > nitrite > chloride > sulfate. The excellent select...
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A synthesized bis(dibenzoylmethanato)Co(II) complex (Co(DBM)(2)), has been used as a ionophore for the preparation of a new perchlorate ion-selective electrode. The electrode exhibits a Nernstian response over the perchlorate concentration range of 8.0x10(-7)-1.0x10(-1)M with a slope of 60.3+/-0.5 mV per decade of concentration. The limit of detection as determined from the intersection of the ...
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A poly(vinyl chloride) membrane based on a new a-dioxime derivative as membrane carrier was prepared andinvestigated as a Cr(III) selective electrode. The electrode exhibits a good potentiometric response for Cr(III)over a wide concentration range 1.0 x 10-6 to 1.0 x 10-1 M with a slope 19.5+0.5 mV/decade and low detectionlimit of 8.9 x 10-7 M. It has a fast response time < 15 s. The best perfo...
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ژورنال
عنوان ژورنال: Analytical Sciences
سال: 2007
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.23.1331